Hi and welcome to siduction.
Pyside6 is not available in Debian Unstable or siduction from the archives. To install it, you need the python-installer pip. First install pip itself with
apt update && apt install python3-pip
In the next step, you install pyside6 with:
pip3 install pyside6
After that, you can start creating Python GUI applications with PySide6 in siduction. Have fun.